Bulk assembly of organic metal halide nanotubes† †Electronic supplementary information (ESI) available. CCDC 1550500. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03675b
نویسندگان
چکیده
Department of Chemical and Biomedic Engineering, Tallahassee, Florida 32310, US Materials Science and Engineering Program Florida 32306, USA National High Magnetic Field Laboratory Florida 32310, USA Department of Chemistry and Biochemistr Florida 32306, USA Department of Chemistry, University of Flo Materials Science & Technology Division and and Systems, Oak Ridge National Laborator † Electronic supplementary information ( and crystallographic data in CIF or 10.1039/c7sc03675b Cite this: Chem. Sci., 2017, 8, 8400
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Post-synthetic halide conversion and selective halogen capture in hybrid perovskites† †Electronic supplementary information (ESI) available. CCDC 1048945–1048947. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01135c
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Redox-promoted associative assembly of metal–organic materials† †Electronic supplementary information (ESI) available: Experimental procedures, compound characterization data, and X-ray crystallographic data for compounds 3–7 and 9–11. CCDC 1405641–1405645, 1429643, 1405647 and 1405648. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02214b Click here for additional data file. Click here for additional data file.
We develop an associative synthesis of metal–organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation. The methodology hinges on the unique reactivity of ortho-quinones, which we introduce as versatile oxidants for mechanochemical synthesis. Our strategy opens a previously unexplored route to paramagnetic metal–...
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